Publications

39. Gaultois, M. W., Grosvenor, A. P. (2012) XANES and XPS investigations of the local structure and final-state effects in
amorphous metal silicates: (ZrO2)x(TiO2)y(SiO2)1-x-y. Physical Chemistry Chemical Physics. 14: 205-217.

38. Hayes, J. R., Grosvenor, A. P. (2011) An X-ray absorption spectroscopic study of the electronic structure and bonding
of rare-earth orthoferrites. Journal of Physics: Condensed Matter. 23: 465502/1-8.

37. Sigrist, J. A., Walker, J. D. S., Hayes, J. R., Gaultois, M. W., Grosvenor, A. P. (2011) Determining the effect of Ru
substitution on the thermal stability of CeFe4-xRuxSb12. Solid State Sciences. 13: 2041-2048.

36. Ramezanipour, F., Greedan, J. E., Siewenie, J., Proffen, Th., Ryan, D. H., Grosvenor, A .P., Donaberger, R. L. (2011)
The local and average structures and magnetic properties of Sr2FeMnO5+y, y = 0.0, 0.5. Comparisons with Ca2FeMnO5
and the effect of the A-site cation. Inorganic Chemistry. 50: 7779-7791.

35. Peddle, J. M., Gaultois, M. W., Grosvenor, A. P. (2011) On the oxidation of EuFe4Sb12 and EuRu4Sb12. Inorganic
Chemistry. 50: 6263-6268.

34. Gaultois, M.W., Greedan, J.E., and Grosvenor, A.P. (2011) Investigation of coordination changes in substituted
transition-metal oxides by K-edge XANES: beyond the pre-edge. Journal of Electron Spectroscopy and Related Phenomena.
184: 192-194.

33. Sigrist, J. A., Gaultois, M. W. and Grosvenor, A. P. (2011) An investigation of the Fe K-edge XANES spectra from
Fe1-xGaxSbO4: local versus non-local excitations. Journal of Physical Chemistry A. 115: 1908-1912.

32. Gaultois, G.W. and Grosvenor, A.P. (2011) XANES and XPS investigations of (TiO2)x(SiO2)1-x: the contribution of
final-state relaxation to shifts in absorption and binding energies. Journal of Materials Chemistry. 21: 1829-1836.

31. Biesinger, M.C., Payne, B.P., Grosvenor, A.P., Lau, L.M.W., Gerson, A. and Smart, R. St. C. (2011) Resolving surface
chemical states in XPS analysis of first row transition-metals, oxides, and hydroxides: Cr, Mn, Fe, Co, and Ni. Applied
Surface Science. 257: 2717-2730.

30. Gaultois, M.W. and Grosvenor, A.P. (2010) Coordination-induced shifts of absorption and binding energies in the
SrFe1-xZnxO3 system. Journal of Physical Chemistry C. 114: 19822-19829.

29. Ramezanipour, F., Greedan, J.E., Grosvenor, A.P., Britten, J.F., Cranswick, L.M.D., and Garlea, V.O. (2010) Intra-layer
cation ordering in a brownmillerite super-structure: synthesis, crystal and magnetic structures of Ca2FeCoO5. Chemistry of
Materials. 22: 6008-6020.

28. Sklad, A.C., Gaultois, M.W., and Grosvenor, A.P. (2010) Examination of CeFe4Sb12 upon exposure to air: is this
material appropriate for use in terrestrial, high-temperature thermoelectric devices? Journal of Alloys and Compounds. 505:
L6-L9.

27. Gaultois, M.W., Grosvenor, A.P., Blanchard, P.E., and Mar, A. (2010) Ternary arsenides Zr(SixAs1-x)As with
PbCl2-type (0 < x < 0.4) and PbFCl-type (x = 0.6) structures. Journal of Alloys and Compounds. 492: 19-25.

26. Blanchard, P.E., Slater, B.R., Cavell, R.G., Mar, A., and Grosvenor, A.P. (2010) Electronic structure of lanthanum
transition-metal oxyarsenides LaMAsO (M=Fe, Co, Ni) and LaFe1-xM'xAsO (M'=Co, Ni) by X-ray photoelectron
spectroscopy. Solid State Sciences. 12: 50-58.

25. Grosvenor, A.P., Ramezanipour, F., Derakhshan, S., Maunders, C., Botton, G.A., and Greedan, J.E. (2009) Effects of
bond-character on the electronic structure of Brownmillerite-phase oxides, Ca2B'xFe2-xO5 (B' = Al, Ga); an X-ray
absorption and electron energy loss spectroscopic study. Journal of Materials Chemistry.19: 9213-9220.

24. Blanchard, P.E.R., Grosvenor, A.P., Cavell, R.G., and Mar, A. (2009) Effects of metal substitution in transition-metal
phosphides (Ni1-xM'x)2P (M' = Cr, Fe, Co) studied by X-ray photoelectron and absorption spectroscopy. Journal of
Materials Chemistry. 19: 6015-6022.

23. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2009) "Bonding and electronic structure of phosphides, arsenides, and
antimonides by X-ray photoelectron and absorption spectroscopies" in Structure and Bonding: Controlled assembly and
Modification of Inorganic Systems. Springer, Berlin. 133: 41-92.

22. Grosvenor, A.P., and Greedan, J.E. (2009) Analysis of metal site preference and electronic structure of
Brownmillerite-phase oxides (A2B'xB2-xO5; A = Ca, Sr; B'/B = Al, Mn, Fe, Co) by X-ray absorption near-edge
spectroscopy. Journal of Physical Chemistry C. 113: 11366-11372.

21. Blanchard, P.E.R., Grosvenor, A.P., Cavell, R.G., and Mar, A. (2008) X-ray photoelectron and absorption spectroscopy
of metal-rich phosphides M2P and M3P (M = Cr - Ni). Chemistry of Materials. 20: 7081-7088.

20. Zelinska, O.Ya., Tkachuk, A.V., Grosvenor, A.P., and Mar, A. (2008) Structure and physical properties of YbZn2Sb2
and YbCd2Sb2. Chemistry of Metals and Alloys. 1: 204-209.

19. Biesinger, M.C., Payne, B.P., Hart, B.R., Grosvenor, A.P., McIntyre, N.S., Lau, L.W.M., and Smart, R.St.C. (2008)
Quantitative chemical state XPS analysis of first row transition metals, oxides and hydroxides. Journal of Physics: Conference
Series. 100: 012025.

18. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2008) Next-nearest neighbour contributions to the XPS binding energies and
XANES absorption energies of P and As in transition-metal arsenide phosphides MAs1-yPy having the MnP-type structure.
Journal of Solid State Chemistry. 181: 2549-2558.

17. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2007) ARXPS study of the ion mobility through (HfO2)x(SiO2)1-x formed
on air-exposed HfSi0.5As1.5. Surface and Interface Analysis. 40: 490-494..

16. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2007) Next-nearest neighbour contribution to P 2p3/2 X-ray photoelectron
binding energy shifts of mixed transition-metal phosphides M1-xM'xP with the MnP-type structure. Journal of Solid State
Chemistry. 180: 2702-2712.

15. Grosvenor, A.P., Cavell, R.G., Mar, A., and Blyth, R.I.R. (2007) Electronic structure of Hf(Si0.5As0.5)As by X-ray
photoelectron and photoemission spectroscopy. Journal of Solid State Chemistry. 180: 2670-2681.

14. Payne, B.P., Grosvenor, A.P., Biesinger, M.C., Kobe, B.A., and McIntyre, N.S. (2007) Structure and growth of oxides
on polycrystalline nickel surfaces. Surface and Interface Analysis. 39: 582-592.

13. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2006) X-ray photoelectron spectroscopy study of the skutterudites
LaFe4Sb12, CeFe4Sb12, CoSb3, and CoP3. Physical Review B. 74: 125102.

12. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2006) X-ray photoelectron spectroscopy study of rare-earth filled
skutterdites LaFe4P12 and CeFe4P12. Chemistry of Materials. 18: 1650-1657.

11. Grosvenor, A.P., Biesinger, M.C., Smart, R.St.-C., and McIntyre, N.S. (2006) New interpretations of XPS spectra of
nickel metal and oxides. Surface Science. 600: 1771-1779.

10. Grosvenor, A.P., Wik, S.D., Cavell, R.G., and Mar, A. (2005) An examination of the bonding in binary transition-metal
monophoshides MP (M = Cr, Mn, Fe, Co) by X-ray photoelectron spectroscopy. Inorganic Chemistry. 44: 8988-8998.

9. McIntyre, N.S., Nie, H.-Y., Grosvenor, A.P., Davidson, R.D., and Briggs, D. (2005) XPS studies of
octadecylphosphonic acid (OPA) monolayer interactions with some metal and mineral surfaces. Surface and Interface
Analysis. 37: 749-754.

8. Grosvenor, A.P., Martin, R.R.H., Giuliacci, M., and Biesinger, M.C. (2005) Evaluation of multiple analytical techniques in
the study of leaching from brass fixtures. Canadian Journal of Analytical Sciences and Spectroscopy. 50: 97-107.

7. Grosvenor, A.P., Francis, J.T., Kobe, B.A., and McIntyre, N.S. (2005) ToF-SIMS studies of the oxidation of Fe by D2O
vapour: a comparison to XPS. Surface and Interface Analysis. 37: 495-498.

6. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2005) Activation energies for the oxidation of iron by oxygen gas and
water vapour. Surface Science. 574: 317-321.

5. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2004) Studies of the oxidation of iron by air after being exposed to
water vapour using angle resolved X-ray photoelectron spectroscopy and QUASES. Surface and Interface Analysis. 36:
1637-1641.

4. Grosvenor, A.P., Kobe, B.A., Biesinger, M.C., and McIntyre, N.S. (2004) Investigation of multiplet splitting of Fe 2p XPS
spectra and bonding in iron compounds. Surface and Interface Analysis. 36: 1564-1574.

3. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2004) Studies of the oxidation of iron by water vapour using X-ray
photoelectron spectroscopy and QUASES. Surface Science. 572: 217-227.

2. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2004) Examination of the oxidation of iron by oxygen using X-ray
photoelectron spectroscopy and QUASES. Surface Science. 565: 151-162.

1. Grosvenor, A.P., Kobe, B.A., McIntyre, N.S., Tougaard, S., and Lennard, W.N. (2004) The use of QUASES/XPS
measurements to determine the oxide composition and thickness on an iron substrate. Surface and Interface Analysis. 36:
632-639.