Publications
82. Beam, J. C., Hehn, A. G., Grosvenor, A. P. (2019) Mixed valence cerium substitution in Gd2-xCexTi2O7 pyrochlores. Journal of Electron Spectroscopy and Related Phenomena. In Press.

81. Bieringer, M., Stewart, J. R., Grosvenor, A. P., Dragomir, M., Greedan, J. E. (2019) The quenching of long range order and the Mn3+ ordered moment in the layered antiferromagnet, BaxSr1-xLaMnO4: A polarized neutron scattering study. Inorganic Chemistry. 58: 4300-4309.

80. Guo, X., Situm, A., Barlow, B. C., Guo, B., Burgess, I.J., Grosvenor, A. P. (2019) Soft X-ray spectromicroscopy studies of pitting corrosion of reinforcing steel bar. Surface and Interface Analysis. 51: 681-691.

79. Sifat, R., Beam, J. C., Grosvenor, A. P. (2019) Investigation of factors that affect the oxidation state of Ce in the garnet-type structure. Inorganic Chemistry. 58: 2299-2306.

78. Situm, A., Guo, X., Guo, B., Barlow, B. C., Burgess, I. J., Grosvenor, A. P (2019) A spectromicroscopy study of the corrosion of fusion-bonded epoxy-coated rebar. Surface and Interface Analysis. 51: 525-530.

77. McMaugherty, S., Grosvenor, A. P. (2019) Low-temperature synthesis of CaZrTi2O7 zirconolite-type materials using ceramic, coprecipitation, and sol-gel methods. Journal of Materials Chemistry C. 7: 177-187.

76. Donato, G., Holzscherer, D., Beam, J. C., Grosvenor, A .P. (2018) A one-step synthesis of rare-earth phosphate-borosilicate glass composites. RSC Advances. 8: 39053-39065.

75. Ebinumoliseh, I., Grosvenor, A. P. (2018) Effect of synthetic method and annealing temperature on the structure of hollandite-type oxides. Inorganic Chemistry. 57: 14353-14361.

74. Situm, A., Guo, X., Barlow, B. C., Guo, B., Burgess, I. J., Grosvenor, A. P. (2018) A spectromicroscopy study of polymer-coated steel. Corrosion Science. 145: 35-46.

73. Barlow, B. C., Situm, A., Guo, B, Guo, X., Grosvenor, A. P., Burgess, I. J. (2018) X-ray microprobe characterization of corrosion at the buried polymer-steel interface. Corrosion Science. 144: 198-206.

72. Rafiuddin, M. R., Grosvenor, A. P. (2018) An investigation of the chemical durability of hydrous and anhydrous rare-earth phosphates. Journal of Nuclear Materials. 509: 631 - 643.

71. Sifat, R., Grosvenor, A. P. (2018) Examination of the site preference in garnet type (X3A2B3O12; X = Y, A/B = Al, Ga, Fe) materials. Solid State Sciences. 83: 56 - 64.

70. Blanchard, P.E.R., Grosvenor, A. P. (2018) Investigating the local structure of B-site cations in (1-x)BaTiO3-xxBiScO3 and (1-x)PbTiO3-xBiScO3 using X-ray absorption spectroscopy. Solid State Sciences. 79: 6-14.

69. Paknahad, E., Grosvenor, A. P. (2017) Investigation of the stability of glass-ceramic composites containing CeTi2O6 and CaZrTi2O7 after ion implantation. Solid State Sciences. 74: 109-117.

68. Aluri, E. R., Bachiu, L. M., Grosvenor, A. P., Forbes, S. H., Greedan, J. E. (2017) Assessing the oxidation states and structural stability of the Ce analogue of brannerite for nuclear waste sequestration applications. Surface and Interface Analysis. 49: 1335-1344.

67. Paknahad, E., Grosvenor, A. P. (2017) Investigation of CeTi2O6- and CaZrTi2O7-containing glass-ceramic composite materials. Canadian Journal of Chemistry. 95: 1110-1121.

66. Rafiuddin, M. R., Grosvenor, A. P. (2016) A structural investigation of hydrous and anhydrous rare-earth phosphates. Inorganic Chemistry. 55: 9185 - 9695.

65. Blanchard, P. E. R., Grosvenor, A. P., Rowson, J., Hughes, K., Brown, C. (2016) Identifying calcium-containing mineral species in the JEB tailings management facility at McClean Lake, Saskatchewan. Applied Geochemistry. 73: 98 - 108.

64. Aluri, E. R., Grosvenor, A. P. (2016) A review of X-ray absorption near-edge spectroscopic studies of pyrochlore-type oxides proposed for nuclear materials applications. Reference Module in Chemistry, Molecular Science and Engineering. 11644-0: 1-14.

63. Grosvenor, A. P., Bellhouse, E. M., Korinek, A., Bugnet, M., McDermid, J. R. (2016) XPS and EELS characterization of Mn2SiO4, MnSiO3, and MnAl2O4. Applied Surface Science. 379: 242 - 248.

62. Hayes, J. R., Grosvenor, A. P., Saoudi, M. (2016) An investigation of the thermal stability of NdxScyZr1-x-yO2 materials proposed for inert matrix fuel applications. Inorganic Chemistry. 55: 1032 - 1043.

61. Hayes, J. R., Grosvenor, A. P. (2016) Investigation of NdxY0.25-xZr0.75O1.88 inert matrix fuel materials made by a co-precipitation synthetic route. Canadian Journal of Chemistry. 94: 198 - 210.

60. Grosvenor, A. P., Biesinger, M. C., Smart, R. St.-C., Gerson, A. R. (2016) "The influence of final-state effects on XPS spectra from first-row transition-metals" in Hard X-ray Photoelectron Spectroscopy (HAXPES). Springer, Berlin. 217 - 262.

59. Aluri, E. R., Grosvenor, A. P. (2015) A study of the electronic structure and structural stability of Gd2Ti2O7 based glass-ceramic composites. RSC Advances. 5: 80939 - 80949.

58. Rafiuddin, M. R., Grosvenor, A. P. (2015) Probing the effect of radiation damage on the structure of rare-earth phosphates. Journal of Alloys and Compounds. 653: 279 - 289.

57. Blanchard, P. E. R., Hayes, J. R., Grosvenor, A. P., Rowson, J., Hughes, K., Brown, C (2015) Investigating the geochemical model for molybdenum mineralization in the JEB tailings management facility at McClean Lake, Saskatchewan: An X-ray absorption spectroscopy study. Environmental Science & Technology. 49: 6504-6509.

56. Thompson, C. M., Chi, L., Hayes, J. R., Hallas, A., Wilson, M., Swainson, I. P., Grosvenor, A. P., Luke, G., Greedan, J. E. (2015) Synthesis, structure, and magnetic properties of novel B-site ordered double perovskites, SrLaMReO6 (M = Mg, Mn, Co and Ni). Dalton Transactions. 44: 10806.

55. Hayes, J. R., Grosvenor, A. P., Saoudi, M. (2015) An investigation of the thermal stability of NdxYyZr1-x-yO2 inert matrix fuel materials. Journal of Alloys and Compounds. 635: 245-255.

54. Aluri, E. R., Grosvenor, A. P. (2014) An investigation of the electronic structure and structural stability of RE2Ti2O7 by glancing angle and total electron yield XANES. Journal of Alloys and Compounds. 616: 516 - 526.

53. Rafiuddin, M. R., Mueller, E., Grosvenor, A. P. (2014) X-ray spectroscopic study of the electronic structure of monazite- and xenotime-type rare-earth phosphates. Journal of Physical Chemistry C. 118: 18000 - 18009.

52. Walker, J. D. S., Hayes, J. R., Grosvenor, A. P. (2014) Examination of the site preference of metals in NiAl2-xGaxO4 spinel-type oxides by X-ray absorption near-edge spectroscopy. Journal of Electron Spectroscopy and Related Phenomena. 195: 139 - 144.

51. Hayes, J. R., Grosvenor, A. P., Rowson, J., Hughes, K., Frey, R. A., Reid, J. (2014) Analysis of the Mo-speciation in the JEB tailings management facility at McClean Lake, Saskatchewan. Environmental Science & Technology. 48: 4460 - 4467.

50. Aluri, E. R., Hayes, J. R., Walker, J. D. S., Grosvenor, A. P. (2014) Investigation of the structural stability of ion implanted Gd2Ti2-xSnxO7 pyrochlore-type oxides by glancing angle X-ray absorption spectroscopy. Journal of Physical Chemistry C.118: 7910 - 7922.

49. Walker, J. D. S., Grosvenor, A. P. (2013) The effect of synthetic method and annealing temperature on metal site preference in Al1-xGaxFeO3. Inorganic Chemistry. 52: 8612 - 8620.

48. Aluri, E. R., Grosvenor, A. P. (2013) An X-ray absorption spectroscopic study of the effect of bond covalency on the electronic structure of Gd2Ti2-xSnxO7. Physical Chemistry Chemical Physics. 15: 10477 - 10486.

47. Revoy, M. N., Scott, R. W. J., Grosvenor, A. P. (2013) Ceria nano-cubes: dependence of the electronic structure on synthetic and experimental conditions. Journal of Physical Chemistry C. 117: 10095 - 10105.

46. Walker, J. D. S., Hayes, J. R., Gaultois, M. W., Aluri, E. R., Grosvenor, A. P. (2013) A case for oxygen deficiency in Gd2Ti2-xZrxO7 pyrochlore-type oxides. Journal of Alloys and Compounds. 565: 44-49.

45. Aluri, E. R., Grosvenor, A. P. (2013) An investigation of pyrochlore-type oxides (Yb2Ti2-xFexO7) by XANES. Journal of Physics and Chemistry of Solids. 74: 830-836.

44. Walker, J. D. S., Grosvenor, A. P. (2013) An X-ray absorption spectrsocopic study of the metal site preference in Al1-xGaxFeO3. Journal of Solid State Chemistry. 197: 147-153.

43. Hayes, J. R., Grosvenor, A. P. (2013) An investigation of the electronic structure of Cu2FeSn3-xTixS8 (0 < x < 3) thiospinel spin-crossover materials by X-ray absorption spectroscopy and electronic structure calculations. Journal of Solid State Chemistry. 197: 532-542.

42. Crerar, S. J., Mar, A., Grosvenor, A. P. (2012) Electronic structure of rare-earth chromium antimonides (RECrSb3 (RE = La-Nd, Sm, Gd-Dy, Yb) by X-ray photoelectron spectroscopy. Journal of Solid State Chemistry. 196: 79-86.

41. Hayes, J. R, Grosvenor, A. P. (2012) An investigation of the Fe and Mo oxidation states in Sr2Fe2-xMoxO6 (0.25<x<1.0) double perovskites by X-ray absorption spectroscopy. Journal of Alloys and Compounds. 537: 323-331.

40. Huynh, L. T., Eger, S. B., Walker, J. D. S., Hayes, J. R., Gaultois, M. W., Grosvenor, A. P. (2012) How temperature influences the stoichiometry of CeTi2O6. Solid State Sciences. 14: 761-767.

39. Gaultois, M. W., Grosvenor, A. P. (2012) XANES and XPS investigations of the local structure and final-state effects in amorphous metal silicates: (ZrO2)x(TiO2)y(SiO2)1-x-y. Physical Chemistry Chemical Physics. 14: 205-217.

38. Hayes, J. R., Grosvenor, A. P. (2011) An X-ray absorption spectroscopic study of the electronic structure and bonding of rare-earth orthoferrites. Journal of Physics: Condensed Matter. 23: 465502/1-8.

37. Sigrist, J. A., Walker, J. D. S., Hayes, J. R., Gaultois, M. W., Grosvenor, A. P. (2011) Determining the effect of Ru substitution on the thermal stability of CeFe4-xRuxSb12. Solid State Sciences. 13: 2041-2048.

36. Ramezanipour, F., Greedan, J. E., Siewenie, J., Proffen, Th., Ryan, D. H., Grosvenor, A .P., Donaberger, R. L. (2011) The local and average structures and magnetic properties of Sr2FeMnO5+y, y = 0.0, 0.5. Comparisons with Ca2FeMnO5 and the effect of the A-site cation. Inorganic Chemistry. 50: 7779-7791.

35. Peddle, J. M., Gaultois, M. W., Grosvenor, A. P. (2011) On the oxidation of EuFe4Sb12 and EuRu4Sb12. Inorganic Chemistry. 50: 6263-6268.

34. Gaultois, M.W., Greedan, J.E., and Grosvenor, A.P. (2011) Investigation of coordination changes in substituted transition-metal oxides by K-edge XANES: beyond the pre-edge. Journal of Electron Spectroscopy and Related Phenomena. 184: 192-194.

33. Sigrist, J. A., Gaultois, M. W. and Grosvenor, A. P. (2011) An investigation of the Fe K-edge XANES spectra from Fe1-xGaxSbO4: local versus non-local excitations. Journal of Physical Chemistry A. 115: 1908-1912.

32. Gaultois, M.W. and Grosvenor, A.P. (2011) XANES and XPS investigations of (TiO2)x(SiO2)1-x: the contribution of final-state relaxation to shifts in absorption and binding energies. Journal of Materials Chemistry. 21: 1829-1836.

31. Biesinger, M.C., Payne, B.P., Grosvenor, A.P., Lau, L.M.W., Gerson, A. and Smart, R. St. C. (2011) Resolving surface chemical states in XPS analysis of first row transition-metals, oxides, and hydroxides: Cr, Mn, Fe, Co, and Ni. Applied Surface Science. 257: 2717-2730.

30. Gaultois, M.W. and Grosvenor, A.P. (2010) Coordination-induced shifts of absorption and binding energies in the SrFe1-xZnxO3 system. Journal of Physical Chemistry C. 114: 19822-19829.

29. Ramezanipour, F., Greedan, J.E., Grosvenor, A.P., Britten, J.F., Cranswick, L.M.D., and Garlea, V.O. (2010) Intra-layer cation ordering in a brownmillerite super-structure: synthesis, crystal and magnetic structures of Ca2FeCoO5. Chemistry of Materials. 22: 6008-6020.

28. Sklad, A.C., Gaultois, M.W., and Grosvenor, A.P. (2010) Examination of CeFe4Sb12 upon exposure to air: is this material appropriate for use in terrestrial, high-temperature thermoelectric devices? Journal of Alloys and Compounds. 505: L6-L9.

27. Gaultois, M.W., Grosvenor, A.P., Blanchard, P.E., and Mar, A. (2010) Ternary arsenides Zr(SixAs1-x)As with PbCl2-type (0 < x < 0.4) and PbFCl-type (x = 0.6) structures. Journal of Alloys and Compounds. 492: 19-25.

26. Blanchard, P.E., Slater, B.R., Cavell, R.G., Mar, A., and Grosvenor, A.P. (2010) Electronic structure of lanthanum transition-metal oxyarsenides LaMAsO (M=Fe, Co, Ni) and LaFe1-xM'xAsO (M'=Co, Ni) by X-ray photoelectron spectroscopy. Solid State Sciences. 12: 50-58.

25. Grosvenor, A.P., Ramezanipour, F., Derakhshan, S., Maunders, C., Botton, G.A., and Greedan, J.E. (2009) Effects of bond-character on the electronic structure of Brownmillerite-phase oxides, Ca2B'xFe2-xO5 (B' = Al, Ga); an X-ray absorption and electron energy loss spectroscopic study. Journal of Materials Chemistry.19: 9213-9220.

24. Blanchard, P.E.R., Grosvenor, A.P., Cavell, R.G., and Mar, A. (2009) Effects of metal substitution in transition-metal phosphides (Ni1-xM'x)2P (M' = Cr, Fe, Co) studied by X-ray photoelectron and absorption spectroscopy. Journal of Materials Chemistry. 19: 6015-6022.

23. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2009) "Bonding and electronic structure of phosphides, arsenides, and antimonides by X-ray photoelectron and absorption spectroscopies" in Structure and Bonding: Controlled assembly and Modification of Inorganic Systems. Springer, Berlin. 133: 41-92.

22. Grosvenor, A.P., and Greedan, J.E. (2009) Analysis of metal site preference and electronic structure of Brownmillerite-phase oxides (A2B'xB2-xO5; A = Ca, Sr; B'/B = Al, Mn, Fe, Co) by X-ray absorption near-edge spectroscopy. Journal of Physical Chemistry C. 113: 11366-11372.

21. Blanchard, P.E.R., Grosvenor, A.P., Cavell, R.G., and Mar, A. (2008) X-ray photoelectron and absorption spectroscopy of metal-rich phosphides M2P and M3P (M = Cr - Ni). Chemistry of Materials. 20: 7081-7088.

20. Zelinska, O.Ya., Tkachuk, A.V., Grosvenor, A.P., and Mar, A. (2008) Structure and physical properties of YbZn2Sb2 and YbCd2Sb2. Chemistry of Metals and Alloys. 1: 204-209.

19. Biesinger, M.C., Payne, B.P., Hart, B.R., Grosvenor, A.P., McIntyre, N.S., Lau, L.W.M., and Smart, R.St.C. (2008) Quantitative chemical state XPS analysis of first row transition metals, oxides and hydroxides. Journal of Physics: Conference Series. 100: 012025.

18. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2008) Next-nearest neighbour contributions to the XPS binding energies and XANES absorption energies of P and As in transition-metal arsenide phosphides MAs1-yPy having the MnP-type structure. Journal of Solid State Chemistry. 181: 2549-2558.

17. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2007) ARXPS study of the ion mobility through (HfO2)x(SiO2)1-x formed on air-exposed HfSi0.5As1.5. Surface and Interface Analysis. 40: 490-494..

16. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2007) Next-nearest neighbour contribution to P 2p3/2 X-ray photoelectron binding energy shifts of mixed transition-metal phosphides M1-xM'xP with the MnP-type structure. Journal of Solid State Chemistry. 180: 2702-2712.

15. Grosvenor, A.P., Cavell, R.G., Mar, A., and Blyth, R.I.R. (2007) Electronic structure of Hf(Si0.5As0.5)As by X-ray photoelectron and photoemission spectroscopy. Journal of Solid State Chemistry. 180: 2670-2681.

14. Payne, B.P., Grosvenor, A.P., Biesinger, M.C., Kobe, B.A., and McIntyre, N.S. (2007) Structure and growth of oxides on polycrystalline nickel surfaces. Surface and Interface Analysis. 39: 582-592.

13. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2006) X-ray photoelectron spectroscopy study of the skutterudites LaFe4Sb12, CeFe4Sb12, CoSb3, and CoP3. Physical Review B. 74: 125102.

12. Grosvenor, A.P., Cavell, R.G., and Mar, A. (2006) X-ray photoelectron spectroscopy study of rare-earth filled skutterdites LaFe4P12 and CeFe4P12. Chemistry of Materials. 18: 1650-1657.

11. Grosvenor, A.P., Biesinger, M.C., Smart, R.St.-C., and McIntyre, N.S. (2006) New interpretations of XPS spectra of nickel metal and oxides. Surface Science. 600: 1771-1779.

10. Grosvenor, A.P., Wik, S.D., Cavell, R.G., and Mar, A. (2005) An examination of the bonding in binary transition-metal monophoshides MP (M = Cr, Mn, Fe, Co) by X-ray photoelectron spectroscopy. Inorganic Chemistry. 44: 8988-8998.

9. McIntyre, N.S., Nie, H.-Y., Grosvenor, A.P., Davidson, R.D., and Briggs, D. (2005) XPS studies of octadecylphosphonic acid (OPA) monolayer interactions with some metal and mineral surfaces. Surface and Interface Analysis. 37: 749-754.

8. Grosvenor, A.P., Martin, R.R.H., Giuliacci, M., and Biesinger, M.C. (2005) Evaluation of multiple analytical techniques in the study of leaching from brass fixtures. Canadian Journal of Analytical Sciences and Spectroscopy. 50: 97-107.

7. Grosvenor, A.P., Francis, J.T., Kobe, B.A., and McIntyre, N.S. (2005) ToF-SIMS studies of the oxidation of Fe by D2O vapour: a comparison to XPS. Surface and Interface Analysis. 37: 495-498.

6. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2005) Activation energies for the oxidation of iron by oxygen gas and water vapour. Surface Science. 574: 317-321.

5. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2004) Studies of the oxidation of iron by air after being exposed to water vapour using angle resolved X-ray photoelectron spectroscopy and QUASES. Surface and Interface Analysis. 36: 1637-1641.

4. Grosvenor, A.P., Kobe, B.A., Biesinger, M.C., and McIntyre, N.S. (2004) Investigation of multiplet splitting of Fe 2p XPS spectra and bonding in iron compounds. Surface and Interface Analysis. 36: 1564-1574.

3. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2004) Studies of the oxidation of iron by water vapour using X-ray photoelectron spectroscopy and QUASES. Surface Science. 572: 217-227.

2. Grosvenor, A.P., Kobe, B.A., and McIntyre, N.S. (2004) Examination of the oxidation of iron by oxygen using X-ray photoelectron spectroscopy and QUASES. Surface Science. 565: 151-162.

1. Grosvenor, A.P., Kobe, B.A., McIntyre, N.S., Tougaard, S., and Lennard, W.N. (2004) The use of QUASES/XPS measurements to determine the oxide composition and thickness on an iron substrate. Surface and Interface Analysis. 36: 632-639.
Grosvenor Group
Copyright 2014 Andrew Grosvenor
Department of Chemistry
University of Saskatchewan
Saskatoon, SK S7N 5C9 Canada
andrew.grosvenor @usask.ca